Substituting Ethanol chemicals instead of Methanol chemicals Doubles the electrical energy that can be stored in a Flow Battery. This is a very Rare discovery. A Flow battery can act like a fuel cell or like a rechargeable battery.

Compound could transform energy storage for large grids

In order to power entire communities with clean energy, such as solar and wind power, a reliable backup storage system is needed to provide energy when the sun isn't shining and the wind doesn't blow. One possibility is to use any excess solar- and wind-based energy to charge solutions of chemicals that can subsequently be stored for use when sunshine and wind are scarce.

From wikipedia, (A flow battery, or redox flow battery (after reduction–oxidation), is a type of electrochemical cell where chemical energy is provided by two chemical components dissolved in liquids contained within the system and separated by a membrane.^[2][3] Ion exchange (accompanied by flow of electric current) occurs through the membrane while both liquids circulate in their own respective space. Cell voltage is chemically determined by the Nernst equation and ranges, in practical applications, from 1.0 to 2.2 volts.

A flow battery may be used like a fuel cell (where the spent fuel is extracted and new fuel is added to the system) or like a rechargeable battery (where an electric power source drives regeneration of the fuel). While it has technical advantages over conventional rechargeables, such as potentially separable liquid tanks and near unlimited longevity, current implementations are comparatively less powerful and require more sophisticated electronics.

The energy capacity is a function of the electrolyte volume (amount of liquid electrolyte) and the power a function of the surface area of the electrodes.)

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From article, (In order to power entire communities with clean energy, such as solar and wind power, a reliable backup storage system is needed to provide energy when the sun isn’t shining and the wind doesn’t blow.

One possibility is to use any excess solar- and wind-based energy to charge solutions of chemicals that can subsequently be stored for use when sunshine and wind are scarce. At that time, the chemical solutions of opposite charge can be pumped across solid electrodes, thus creating an electron exchange that provides power to the electrical grid.

The key to this technology, called a redox flow battery, is finding chemicals that can not only “carry” sufficient charge, but also be stored without degrading for long periods, thereby maximizing power generation and minimizing the costs of replenishing the system.

University of Rochester researchers, working with colleagues at the University at Buffalo, believe they have found a promising compound that could transform the energy storage landscape.

In a paper published in Chemical Science, an open access journal of the Royal Society of Chemistry, researchers in the lab of Ellen Matson, assistant professor of chemistry, describe modifying a metal-oxide cluster, which has promising electroactive properties, so that it is nearly twice as effective as the unmodified cluster for electrochemical energy storage in a redox flow battery.

“Energy storage applications with polyoxometalates are pretty rare in the literature,” says lead author Lauren VanGelder, a third-year PhD student in Matson’s lab. “There are maybe one or two examples prior to ours, and they didn’t really maximize the potential of these systems.”

“This is really an untapped area of molecular development,” adds Matson.

The cluster was first developed in the lab of German chemist Johann Spandl, and studied for its magnetic properties. Tests conducted by VanGelder showed that the compound could store charge in a redox flow battery, “but was not as stable as we had hoped.”

However, by making what Matson describes as “a simple molecular modification”— replacing the compound’s methanol-derived methoxide groups with ethanol-based ethoxide ligands—the team was able to expand the potential window during which the cluster was stable, doubling the amount of electrical energy that could be stored in the battery.

Says Matson: “What’s really cool about this work is the way we can generate the ethoxide and methoxide clusters by using methanol and ethanol. Both of these reagents are inexpensive, readily available and safe to use. The metal and oxygen atoms that compose the remainder of the cluster are earth-abundant elements. The straightforward, efficient synthesis of this system is a totally new direction in charge-carrier development that, we believe, will set a new standard in the field.”)

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